Ultrasonic Studies and Molecular Interactions of N, N-Dimethyl Formamide and 1-Butanol with n-Hexane at Different Temperatures 303K ,308K and 313K.

  • Syed Ibrahim P.S. Assistant Professor, Dept of Chemistry, Sriram Engineering College, Perumalpattu, Thiruvallur, Tamil Nadu
  • Chidambaravinayagam S Associate Professor, PG and Research Department of Chemistry, Presidency College, Chennai, Tamil Nadu.
  • Senthil Murugan J Assistant Professor, Department of Chemistry, SIVET college, Chennai, Tamil Nadu.
  • Edward Jeyakumar J Research Scholar, PG and Research Department of Chemistry, Presidency College, Chennai, Tamil Nadu
Keywords: molecular interactions, ternary liquid mixture, adiabatic compressibility, internal pressure, acoustic impedence

Abstract

The Ultrasonic velocity(U), density(ρ), and viscosity(ȵ) have been measured for the ternary liquid mixtures of N,N-Dimethyl Formamide (NNDMF),   1 butanol and n hexane at various temperatures viz., 303 k,308 k and 313 k at constant frequency 2 MHz. for different concentrations ranges from 0.001M to 0.01M. The acoustical parameters such as adiabatic compressibility(β), Rao constant(R), absorption coefficient (α/f2), internal pressure(πi), cohesive energy(CE), free volume(Vf), free length(Lf) and acoustic impedence(z), were calculated from the experimental data. These parameters in accordance with their ultrasonic velocities corresponding to different concentrations were discussed.

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Published
2019-05-25
How to Cite
P.S., S. I., S, C., J, S. M., & J, E. J. (2019). Ultrasonic Studies and Molecular Interactions of N, N-Dimethyl Formamide and 1-Butanol with n-Hexane at Different Temperatures 303K ,308K and 313K. International Research Journal of Multidisciplinary Technovation, 1(3), 1-7. Retrieved from https://mapletreejournals.com/index.php/irjmt/article/view/233